Rate Law Equation:
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The Method of Initial Rates is a technique used to determine the rate law of a chemical reaction by measuring the initial rate of reaction at different reactant concentrations while keeping other conditions constant.
The calculator uses the rate law equation:
Where:
Explanation: The equation calculates the rate constant from experimental data of initial rates at known concentrations.
Details: The rate constant is fundamental to understanding reaction kinetics, predicting reaction rates under different conditions, and designing chemical processes.
Tips: Enter initial rate in M/s, reactant concentration in M, and the reaction order (can be fractional). All values must be positive numbers.
Q1: What are typical units for k?
A: Units vary with reaction order: M⁻¹s⁻¹ for 2nd order, s⁻¹ for 1st order, M¹⁻ⁿs⁻¹ where n is overall order.
Q2: How is reaction order determined?
A: By comparing how rate changes with concentration changes in multiple experiments.
Q3: What's the difference between rate and rate constant?
A: Rate is speed of reaction at specific conditions; rate constant is proportionality factor in rate law.
Q4: Can this be used for complex reactions?
A: Only for elementary reactions or when the rate law is known from initial rate experiments.
Q5: What affects the rate constant?
A: Temperature (via Arrhenius equation) and catalyst presence, but not concentrations.