Arrhenius Equation:
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The Arrhenius equation describes the temperature dependence of reaction rates. It relates the rate constant (k) of a chemical reaction to the temperature (T), activation energy (Ea), and pre-exponential factor (A).
The calculator uses the Arrhenius equation:
Where:
Explanation: The equation shows how the rate constant increases with temperature and decreases with higher activation energy.
Details: The rate constant is fundamental in chemical kinetics, used to predict reaction rates under different conditions and design chemical processes.
Tips: Enter the pre-exponential factor in 1/s, activation energy in J/mol, and temperature in Kelvin. All values must be positive.
Q1: What are typical values for the pre-exponential factor?
A: For simple reactions, A is typically 10^10 to 10^13 1/s, but can vary widely depending on the reaction.
Q2: How does temperature affect the rate constant?
A: Generally, increasing temperature increases the rate constant exponentially, as described by the Arrhenius equation.
Q3: What is the significance of activation energy?
A: Activation energy represents the minimum energy required for a reaction to occur. Higher Ea means slower reaction at a given temperature.
Q4: Can this equation be used for all reactions?
A: The Arrhenius equation works well for elementary reactions but may need modification for complex reactions.
Q5: Why use Kelvin for temperature?
A: The Arrhenius equation requires absolute temperature to properly account for the exponential relationship between temperature and reaction rate.