Rate Constant Equation:
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The specific rate constant (k) is a proportionality constant that relates the reaction rate to the reactant concentrations raised to the power of their respective orders in the rate law equation. It is specific to a particular reaction at a given temperature.
The calculator uses the rate law equation:
Where:
Explanation: The equation shows how the rate constant relates the reaction rate to the concentrations of the reactants and their reaction orders.
Details: The rate constant is fundamental in chemical kinetics as it allows prediction of reaction rates under different conditions and provides insight into reaction mechanisms.
Tips: Enter the reaction rate in mol/L·s, reactant concentration in mol/L, and the reaction order (sum of exponents in rate law). All values must be positive.
Q1: What are the units of the rate constant?
A: The units vary with the overall reaction order. For order n, units are (mol/L)1-n·s-1.
Q2: How does temperature affect the rate constant?
A: According to the Arrhenius equation, rate constant increases exponentially with temperature.
Q3: What's the difference between rate and rate constant?
A: Rate measures how concentration changes with time, while rate constant is the proportionality factor in the rate law.
Q4: Can this be used for elementary reactions?
A: Yes, for elementary reactions the orders equal the stoichiometric coefficients.
Q5: How is this related to half-life?
A: For first-order reactions, half-life (t½) = ln(2)/k.