Arrhenius Equation:
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The Arrhenius equation describes the temperature dependence of reaction rates. The two-point form calculates activation energy (Ea) from rate constants at two different temperatures.
The calculator uses the two-point Arrhenius equation:
Where:
Explanation: The equation relates the natural logarithm of the rate constant ratio to the inverse temperature difference.
Details: Activation energy represents the minimum energy needed for a chemical reaction to occur. It helps predict reaction rates at different temperatures and understand reaction mechanisms.
Tips: Enter rate constants in 1/s and temperatures in Kelvin. All values must be positive, and temperatures must be different.
Q1: What units should I use?
A: Rate constants in 1/s, temperatures in Kelvin. The result is in J/mol (divide by 1000 for kJ/mol).
Q2: Why must temperatures be different?
A: The denominator would be zero with identical temperatures, making the equation undefined.
Q3: What's a typical range for Ea?
A: Most reactions have Ea between 50-250 kJ/mol (50,000-250,000 J/mol).
Q4: Can I use Celsius temperatures?
A: No, you must convert to Kelvin first (K = °C + 273.15).
Q5: How accurate is this method?
A: For precise results, measure rate constants at multiple temperatures and perform linear regression on an Arrhenius plot.