Graham's Law of Effusion:
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Graham's Law states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. This principle is important in understanding gas diffusion and separation processes.
The calculator uses Graham's Law equation:
Where:
Explanation: The equation shows that lighter gases effuse faster than heavier ones. For example, hydrogen (M = 2 g/mol) effuses much faster than oxygen (M = 32 g/mol).
Details: Understanding effusion rates is crucial in chemical engineering, gas separation technologies, and predicting gas behavior in different environments.
Tips: Enter the molar mass of the gas in g/mol. The value must be greater than 0. The calculator will output the relative effusion rate.
Q1: What's the difference between effusion and diffusion?
A: Effusion is gas escaping through a tiny hole, while diffusion is gas spreading out in space. Both follow similar principles but differ in their mechanisms.
Q2: How do I compare effusion rates of two gases?
A: The ratio of effusion rates is equal to the inverse ratio of the square roots of their molar masses: \( \frac{r_1}{r_2} = \sqrt{\frac{M_2}{M_1}} \).
Q3: What are typical molar mass values?
A: Common gases range from 2 g/mol (H₂) to 44 g/mol (CO₂). Air averages about 29 g/mol.
Q4: Does temperature affect effusion rate?
A: While Graham's Law focuses on molar mass, temperature does affect absolute effusion rates (higher temperature = faster effusion).
Q5: What practical applications use this principle?
A: Gas separation processes, leak detection, and isotope separation (like uranium enrichment) all utilize Graham's Law principles.